Dealloying Synthesis of Bimetallic (Au-Pd)/CeO₂ Catalysts for CO Oxidation.

ABSTRACT: The nanorod-structured (Au-Pd)/CeO₂ catalysts with different Au/Pd ratios were prepared from Al-Ce-Au-Pd precursor alloys through combined dealloying and calcination treatment. XRD, SEM, TEM, XPS, Raman spectroscopy, and N₂ adsorption-desorption measurements were applied to test the structure and physicochemical properties of samples. Catalytic evaluation results imply that the (Pd_0.15-Au_0.15)/CeO₂ catalyst calcined at 500 °C possesses optimal catalytic activity for CO oxidation when compared with other catalysts with different Au/Pd ratios or (Pd_0.15-Au_0.15)/CeO₂ calcined at other temperatures, whose 50% and 99% reaction temperature can be reached as low as 50 and 85 °C, respectively. This superior cat

SUBMITTER: Wang H 

PROVIDER: S-EPMC10077571 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature