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Analysis and process evaluation of metal dopant (Zr, Cr)-promoted Ga-modified ZSM-5 for the oxidative dehydrogenation of propane in the presence and absence of CO2.


ABSTRACT: A systematic study of the comparative performances of 4% Ga-, 4% Zr-, and 1% Cr-impregnated H-ZSM-5 catalysts for oxidative dehydrogenation of propane in the presence and absence of CO2 is presented. It was found that methane, ethene, propene, butene, pentene, and BTX are the major products from all of these catalysts at various reaction temperatures (400-550 °C), WHSV, 4 kgcat s molC3H8 -1 and feed gas, C3H8/N2 = 2.5/97.5 and C3H8/CO2/N2 = 2.5/5/92.5; flow rate, 75 mL min-1 under atmospheric pressure for 10 h. The combination of material characterization and catalytic testing revealed that Ga-, Zr-, and Cr-doped H-ZSM-5 are excellent cat

SUBMITTER: Jawad A 

PROVIDER: S-EPMC10077947 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature