Pressure-Induced Structural Effects in the Square Lattice (sql) Topology Coordination Network Sql-1-Co-NCS·4OX.

ABSTRACT: A high-pressure study of a switching coordination network of square lattice topology (sql) loaded with o-xylene (OX), [Co(4,4'-bipyridine)₂(NCS)₂] _n ·4nC₈H₁₀ (sql-1-Co-NCS·4OX), was conducted up to approximately 1 GPa to investigate pressure-induced structural changes. Previous reports revealed that sql-1-Co-NCS exhibits multiple phases thanks to its ability to switch between closed (nonporous) and several open (porous) phases in the presence of various gases, vapors, and liquids. Networks of such properties are of topical interest because they can offer high working capacity and improved recyclability for gas adsorption. The monoclinic crystal structure of sql-1-Co-NCS·4OX at 100 K was previously reported to show

SUBMITTER: Patyk-Kazmierczak E 

PROVIDER: S-EPMC10080653 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature