Support Pore Structure and Composition Strongly Influence the Direct Air Capture of CO₂ on Supported Amines.

ABSTRACT: A variety of amine-impregnated porous solid sorbents for direct air capture (DAC) of CO₂ have been developed, yet the effect of amine-solid support interactions on the CO₂ adsorption behavior is still poorly understood. When tetraethylenepentamine (TEPA) is impregnated on two different supports, commercial γ-Al₂O₃ and MIL-101(Cr), they show different trends in CO₂ sorption when the temperature (-20 to 25 °C) and humidity (0-70% RH) of the simulated air stream are varied. In situ IR spectroscopy is used to probe the mechanism of CO₂ sorption on the two supported amine materials, with weak chemisorption (formation of carbamic acid) being the dominant pathway over MIL-101(Cr)-supported TEPA and strong chemisorption (form

SUBMITTER: Rim G 

PROVIDER: S-EPMC10080690 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature