Realizing efficient blue and deep-blue delayed fluorescence materials with record-beating electroluminescence efficiencies of 43.4.

ABSTRACT: As promising luminescent materials for organic light-emitting diodes (OLEDs), thermally activated delayed fluorescence materials are booming vigorously in recent years, but robust blue ones still remain challenging. Herein, we report three highly efficient blue and deep-blue delayed fluorescence materials comprised of a weak electron acceptor chromeno[3,2-c]carbazol-8(5H)-one with a rigid polycyclic structure and a weak electron donor spiro[acridine-9,9'-xanthene]. They hold distinguished merits of excellent photoluminescence quantum yields (99%), ultrahigh horizontal transition dipole ratios (93.6%), and fast radiative transition and reverse intersystem crossing, which furnish superb blue and deep-blue electroluminescence with Commission Internationale de I'Eclairage coordinates (CIE

SUBMITTER: Fu Y 

PROVIDER: S-EPMC10086064 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature