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Magneto-structural studies on a number of doubly end-on cyanate and azide bridged dinuclear nickel(ii) complexes with {N₃O} donor Schiff base ligands.

ABSTRACT: Two new doubly μ _1,1-N₃ bridged (1 and 3) and six new doubly μ _1,1-NCO bridged Ni^II complexes (2, 4-8) with six different N₃O donor Schiff base ligands have been synthesized and magneto-structurally characterized. All these neutral complex molecules are isostructural and constitute edge sharing bioctahedral structures. Magnetic studies revealed that all these complexes exhibit ferromagnetic interaction through bridging pseudohalides with ferromagnetic coupling constant J being significantly higher for azide-bridged complexes than that of the cyanate analogues. This is consistent with the literature reported data and also the presence of polarizable π systems and two different N and O donor atoms in cyanate ion, ren

SUBMITTER: Jana NC

PROVIDER: S-EPMC10088076 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature

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Magneto-structural studies on a number of doubly end-on cyanate and azide bridged dinuclear nickel(ii) complexes with {N₃O} donor Schiff base ligands.

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Magneto-structural studies on a number of doubly end-on cyanate and azide bridged dinuclear nickel(ii) complexes with {N3O} donor Schiff base ligands.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Magneto-structural studies on a number of doubly end-on cyanate and azide bridged dinuclear nickel(ii) complexes with {N₃O} donor Schiff base ligands.