The Glass Transition Temperature of Heterogeneous Biopolymer Systems.

ABSTRACT: Biopolymers are abundant, renewable, and biodegradable resources. However, bio-based materials often require toughening additives, like (co)polymers or small plasticizing molecules. Plasticization is monitored via the glass transition temperature versus diluent content. To describe this, several thermodynamic models exist; nevertheless, most expressions are phenomenological and lead to over-parametrization. They also fail to describe the influence of sample history and the degree of miscibility via structure-property relationships. We propose a new model to deal with semi-compatible systems: the generalized mean model, which can classify diluent segregation or partitioning. When the constant k_GM is below unity, the addition of plasticizers has hardly any effect, and in so

SUBMITTER: Espindola SP 

PROVIDER: S-EPMC10091355 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature