CoO-Co Heterojunction Covered with Carbon Enables Highly Efficient Integration of Hydrogen Evolution and 5-Hydroxymethylfurfural Oxidation.

ABSTRACT: The renewable-energy-driven integration of hydrogen production and biomass conversion into value-added products is desirable for the current global energy transition, but still a challenge. Herein, carbon-coated CoO-Co heterojunction arrays were built on copper foam (CoO-Co@C/CF) by the carbothermal reduction to catalyze the hydrogen evolution reaction (HER) coupled with a 5-hydroxymethylfurfural electrooxidation reaction (HMFEOR). The electronic modulation induced by the CoO-Co heterojunction endows CoO-Co@C/CF with a powerful catalytic ability. CoO-Co@C/CF is energetic for HER, yielding an overpotential of 69 mV at 10 mA·cm^-1 and Tafel slope of 58 mV·dec^-1. Meanwhile, CoO-Co@C/CF delivers an excellent electrochemical activity for the selective conversion from HMF in

SUBMITTER: Zhao L 

PROVIDER: S-EPMC10096219 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature