Promotion of the Efficient Electrocatalytic Production of H₂O₂ by N,O- Co-Doped Porous Carbon.

ABSTRACT: H₂O₂ generation via an electrochemical two-electron oxygen reduction (2e^- ORR) is a potential candidate to replace the industrial anthraquinone process. In this study, porous carbon catalysts co-doped by nitrogen and oxygen are successfully synthesized by the pyrolysis and oxidation of a ZIF-67 precursor. The catalyst exhibits a selectivity of ~83.1% for 2e^- ORR, with the electron-transferring number approaching 2.33, and generation rate of 2909.79 mmol g^-1 h^-1 at 0.36 V (vs. RHE) in KOH solution (0.1 M). The results prove that graphitic N and -COOH functional groups act as the catalytic centers for this reaction, and the two functional groups work together to greatly enhance the performance of 2e^- ORR. In additio

SUBMITTER: Sun L 

PROVIDER: S-EPMC10096704 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature