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Enhanced Water Adsorption of MIL-101(Cr) by Metal-Organic Polyhedral Encapsulation for Adsorption Cooling.


ABSTRACT: Metal-organic frameworks (MOFs) are one of the most promising adsorbents in the adsorption cooling system (ACS) for their outstanding water adsorption performance. Notwithstanding that fact, numerous reports pay more attention to the ACS performance improvement through enhancing equilibrium water uptake of MOFs. However, adsorption cooling performance, including specific cooling power (SCP) and coefficient of performance for cooling (COPC) of MOF/water working pairs, always depends on the water adsorption kinetics of MOFs in ACS. In this work, to increase the water adsorption rate, the preparation of MOP/MIL-101(Cr) was achieved by encapsulating hydrophilic metal-organic polyhedral (MOP) into MIL-101(Cr). It was found that the hydrophilicity of MOP/MIL-101(Cr) was enhanced upon

SUBMITTER: Xia X 

PROVIDER: S-EPMC10096998 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature