Multi-Block Copolymer Membranes Consisting of Sulfonated Poly(p-phenylene) and Naphthalene Containing Poly(arylene Ether Ketone) for Proton Exchange Membrane Water Electrolysis.

ABSTRACT: Glassy hydrocarbon-based membranes are being researched as a replacement for perfluorosulfonic acid (PFSA) membranes in proton exchange membrane water electrolysis (PEMWE). Here, naphthalene containing Poly(arylene Ether Ketone) was introduced into the Poly(p-phenylene)-based multi-block copolymers through Ni(0)-catalyzed coupling reaction to enhance π-π interactions of the naphthalene units. It is discovered that there is an optimum input ratio of the hydrophilic monomer and NBP oligomer for the multi-block copolymers with high ion exchange capacity (IEC) and polymerization yield. With the optimum input ratio, the naphthalene containing copolymer exhibits good hydrogen gas barrier property, chemical stability, and mechanical toughness, even with its high IEC value over 2.4 m

SUBMITTER: Ko EJ 

PROVIDER: S-EPMC10097103 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature