Reactivity of Sodium Pentaphospholide Na[cyclo-P₅ ] towards C≡E (E=C, N, P) Triple Bonds.

ABSTRACT: A diglyme solution of Na[cyclo-P₅ ] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2 a-c, 4 a,b, and 6. The reaction of Na[cyclo-P₅ ] with alkynes and nitriles was studied by means of DFT methods, which suggested a concerted mechanism for the formation of 2 a and 4 b. The anions 2 a-c, 4 a,b, and 6 coordinate in an η⁵ -fashion towards Fe^II to give the sandwich (aza)phosphametallocenes 3 a-c, 5 a,b and 7 in moderate to good yields. The new compounds were characterized by means of multinuclear NMR spectroscopy, single-crystal X-ray diffraction and cyclic voltammetry.

SUBMITTER: Petrov A 

PROVIDER: S-EPMC10098531 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature