Vinylene-Linked 2D Conjugated Covalent Organic Frameworks by Wittig Reactions.

ABSTRACT: Vinylene-linked two-dimensional covalent organic frameworks (V-2D-COFs) have shown great promise in electronics and optoelectronics. However, only a few reactions for V-2D-COFs have been developed hitherto. Besides the kinetically low reversibility of C=C bond formation, another underlying issue facing the synthesis of V-2D-COFs is the attainment of high (E)-alkene selectivity to ensure the appropriate symmetry of 2D frameworks. Here, we tailor the E/Z selectivity of the Wittig reaction by employing a proper catalyst (i.e., Cs₂ CO₃ ) to obtain more stable intermediates and elevating the temperature across the reaction barrier. Subsequently, the Wittig reaction is innovatively utilized for the synthesis of four crystalline V-2D-COFs by combining aldehydes and ylides. I

SUBMITTER: Liu Y 

PROVIDER: S-EPMC10098612 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature