Electrochemical Palladium-Catalyzed Oxidative Carbonylation-Cyclization of Enallenols.

ABSTRACT: Herein, we report an electrochemical oxidative palladium-catalyzed carbonylation-carbocyclization of enallenols to afford γ-lactones and spirolactones, which proceeds with excellent chemoselectivity. Interestingly, electrocatalysis was found to have an accelerating effect on the rate of the tandem process, leading to a more efficient reaction than that under chemical redox conditions.

SUBMITTER: Zhang J 

PROVIDER: S-EPMC10098644 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature