Coordination of Pnictogenylboranes Towards Tl(I) Salts and a Tl- Mediated P-P Coupling.

ABSTRACT: The coordination chemistry of only Lewis-base (LB)-stabilized pnictogenylboranes EH₂ BH₂ ⋅NMe₃ (E=P, As) towards Tl(I) salts has been studied. The reaction of Tl[BAr^Cl ] (BAr^Cl =[B(3,5-C₆ H₃ Cl₂ )₄ ]^- ) with the corresponding pnictogenylborane results in the formation of [Tl(EH₂ BH₂ ⋅NMe₃ )][BAr^Cl ] (1 a: E=P; 1 b: E=As). Whereas the Tl ion in 1 a/b is monocoordinated, the exchange of the weakly coordinating anion (WCA) in the Tl(I) salt leads to the formation of a trigonal pyramidal coordination mode at the Tl atom by coordination of three equivalents of EH₂ BH₂  ⋅ NMe₃ in [Tl(EH₂ BH₂

SUBMITTER: Szlosek R 

PROVIDER: S-EPMC10099240 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature