Synthesis, Post-Functionalization and Properties of Diphosphapentaarenes.

ABSTRACT: Linearly-fused polyarenes are an important class of compounds with high relevance in materials science. While modifying the shape and size represents a common means to fine-tune their properties, the precise placement of heteroatoms is a strategy that is receiving an increasing deal of attention to overcome the intrinsic limitations of all-carbon structures. Thus, linearly-fused diphosphaarenes recently emerged as a novel family of molecules with striking optoelectronic properties and outstanding stability. However, the properties of diphosphaarenes are far from being benchmarked. Herein, we report the synthesis, phosphorus post-functionalization and properties of new diphosphapentaarene derivatives. We describe their synthetic limitations and unveil their potential for optoelectronic appl

SUBMITTER: Regulska E 

PROVIDER: S-EPMC10100039 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature