Activation of Ge-H and Sn-H Bonds with N-Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene.

ABSTRACT: A study of the reactivity of several N-heterocyclic carbenes (NHCs) and the cyclic (alkyl)(amino)carbene 1-(2,6-di-iso-propylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene (cAAC^Me ) with the group 14 hydrides GeH₂ Mes₂ and SnH₂ Me₂ (Me=CH₃ , Mes=1,3,5-(CH₃ )₃ C₆ H₂ ) is presented. The reaction of GeH₂ Mes₂ with cAAC^Me led to the insertion of cAAC^Me into one Ge-H bond to give cAAC^Me H-GeHMes₂ (1). If 1,3,4,5-tetramethyl-imidazolin-2-ylidene (Me₂ Im^Me ) was used as the carbene, NHC-mediated dehydrogenative coupling occurred, which led to the NHC-stabilized germylene Me₂ Im^Me

SUBMITTER: Philipp MSM 

PROVIDER: S-EPMC10100474 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature