Colloidal CsPbX3 Nanocrystals with Thin Metal Oxide Gel Coatings.
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ABSTRACT: Lead halide perovskite (LHP) nanocrystals (NCs) have gathered much attention as light-emitting materials, particularly owing to their excellent color purity, band gap tunability, high photoluminescence quantum yield (PLQY), low cost, and scalable synthesis. To enhance the stability of LHP NCs, bulky strongly bound organic ligands are commonly employed, which counteract the extraction of charge carriers from the NCs and hinder their use as photoconductive materials and photocatalysts. Replacing these ligands with a thin coating is a complex challenge due to the highly dynamic ionic lattice, which is vulnerable to the commonly employed coating precursors and solvents. In this work, we demonstrate thin (<1 nm) metal oxide gel coatings through non-hydrolytic sol-gel reactions. The coated NCs a
SUBMITTER: Guggisberg D
PROVIDER: S-EPMC10100534 | biostudies-literature | 2023 Apr
REPOSITORIES: biostudies-literature
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