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Self-Assembly of Bi2Sn2O7/β-Bi2O3 S-Scheme Heterostructures for Efficient Visible-Light-Driven Photocatalytic Degradation of Tetracycline.


ABSTRACT: Fabrication of S-scheme heterojunctions with enhanced redox capability offers an effective approach to address environmental remediation. In this study, high-performance Bi2Sn2O7/β-Bi2O3 S-scheme heterojunction photocatalysts were fabricated via the in situ growth of Bi2Sn2O7 on β-Bi2O3 microspheres. The optimized Bi2Sn2O7/β-Bi2O3 (BSO/BO-0.4) degradation efficiency for tetracycline hydrochloride was 95.5%, which was 2.68-fold higher than that of β-Bi2O3. This improvement originated from higher photoelectron-hole pair separation efficiency, more exposed active sites, excellent redox capacity, and efficient generation of ·O2 - and ·OH. Additionally, Bi2Sn2O7/β-Bi2O3 exhibited good stability against photocatalytic degradation, and the degradation efficiency remained >89.7% after five cycles. The photocatalytic mechanism of Bi2Sn2O7/β-Bi2O3 S-scheme heterojunctions was elucidated. In this study, we design and fabricate high-performance heterojunction photocatalysts for environmental remediation using S-scheme photocatalysts.

SUBMITTER: Zhu B 

PROVIDER: S-EPMC10116523 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature

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Self-Assembly of Bi<sub>2</sub>Sn<sub>2</sub>O<sub>7</sub>/β-Bi<sub>2</sub>O<sub>3</sub> S-Scheme Heterostructures for Efficient Visible-Light-Driven Photocatalytic Degradation of Tetracycline.

Zhu Baikang B   Dong Qinbin Q   Huang Jianghua J   Yang Mengmeng M   Chen Xianlei X   Zhai Chunyang C   Chen Qingguo Q   Wang Bohong B   Tao Hengcong H   Chen Li L  

ACS omega 20230406 15


Fabrication of S-scheme heterojunctions with enhanced redox capability offers an effective approach to address environmental remediation. In this study, high-performance Bi<sub>2</sub>Sn<sub>2</sub>O<sub>7</sub>/β-Bi<sub>2</sub>O<sub>3</sub> S-scheme heterojunction photocatalysts were fabricated via the in situ growth of Bi<sub>2</sub>Sn<sub>2</sub>O<sub>7</sub> on β-Bi<sub>2</sub>O<sub>3</sub> microspheres. The optimized Bi<sub>2</sub>Sn<sub>2</sub>O<sub>7</sub>/β-Bi<sub>2</sub>O<sub>3</sub> (B  ...[more]

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