Carbazole fluorophore with an imidazole/thiazole unit: contrasting stimuli-induced fluorescence switching, water-sensing and deep-blue emission.

ABSTRACT: Carbazole-based, π-conjugated donor-acceptor fluorophores were synthesized by integrating imidazole/thiazole units. Then, we investigated the impact of subtle structural changes on fluorescence properties. Carbazole integrated with imidazole (Cz-I) and carbazole integrated with thiazole (Cz-T) showed strong fluorescence in solution (quantum yield (Φ _f) = 0.18 (Cz-I) and 0.14 (Cz-T) compared with the standard quinine sulfate) and solid-state (Φ _f = 8.0% (Cz-I) and 14.6% (Cz-T)). Cz-I showed relatively more blue-shifted emission in solution compared with the solid-state (λ _max = 417 nm (CH₃CN) and 460 nm (solid)). Cz-T exhibited deep-blue emission in the solid-state compared with solution (λ _max = 455 nm (CH

SUBMITTER: Ravi S 

PROVIDER: S-EPMC10119750 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature