A 4H⁺/4e^- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex.

ABSTRACT: In this research article, we describe a 4H⁺/4e^- electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. The protonated/reduced ECPB (complex 1: [Cu(8H⁺/14e^-)]¹⁺), consisting of Cu^I with 2 equiv of the ligand (^catLH₄: 1,1'-(4,5-dimethoxy-1,2-phenylene)bis(3-(tert-butyl)urea)), reacted with H⁺/e^- acceptors such as O₂ to generate the deprotonated/oxidized ECPB. The resulting compound, (complex 5: [Cu(4H⁺/10e^-)]¹⁺), was characterized by X-ray diffraction analysis, nuclear magnetic resonance (¹H-NMR), and density functional theory, and it is electronically described as a cuprou

SUBMITTER: Wu T 

PROVIDER: S-EPMC10123533 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature