High-efficiency and stable short-delayed fluorescence emitters with hybrid long- and short-range charge-transfer excitations.

ABSTRACT: The pursuit of ideal short-delayed thermally activated delayed fluorescence (TADF) emitters is hampered by the mutual exclusion of a small singlet-triplet energy gap (ΔE_ST) and a large oscillator strength (f). Here, by attaching an multiresonance-acceptor onto a sterically-uncrowded donor, we report TADF emitters bearing hybrid electronic excitations with a main donor-to-acceptor long-range (LR) and an auxiliary bridge-phenyl short-range (SR) charge-transfer characters, balancing a small ΔE_ST and a large f. Moreover, the incorporation of dual equivalent multiresonance-acceptors is found to double the f value without affecting the ΔE_ST. A large radiative decay rate over an order of magnitude higher than the intersystem crossing (ISC) rate, and a decent rever

SUBMITTER: Meng G 

PROVIDER: S-EPMC10133342 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature