Facial Preparation of Cyclometalated Iridium (III) Nanowires as Highly Efficient Electrochemiluminescence Luminophores for Biosensing.

ABSTRACT: In this study, highly efficient ECL luminophores composed of iridium complex-based nanowires (Ir-NCDs) were synthesized via covalently linking bis(2-phenylpyridine)-(4-carboxypropyl-2,2'-bipyridyl) iridium(III) hexafluorophosphate with nitrogen-doped carbon quantum dots (NCDs). The ECL intensity of the nanowires showed a five-fold increase in ECL intensity compared with the iridium complex monomer under the same experimental conditions. A label-free ECL biosensing platform based on Ir-NCDs was established for Salmonella enteritidis (SE) detection. The ECL signal was quenched linearly in the range of 10²-10⁸ CFU/mL for SE with a detection limit of 10² CFU/mL. Moreover, the relative standard deviations (RSD) of the stability within and between batches

SUBMITTER: Huang Y 

PROVIDER: S-EPMC10136454 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature