Cobalt and Iron Phthalocyanine Derivatives: Effect of Substituents on the Structure of Thin Films and Their Sensor Response to Nitric Oxide.

ABSTRACT: In this work, we study the effect of substituents in cobalt(II) and iron(II) phthalocyanines (CoPcR₄ and FePcR₄ with R = H, F, Cl, tBu) on the structural features of their films, and their chemi-resistive sensor response to a low concentration of nitric oxide. For the correct interpretation of diffractograms of phthalocyanine films, structures of CoPcCl₄ and FePcCl₄ single crystals were determined for the first time. Films were tested as active layers for the determination of low concentrations of NO (10-1000 ppb). It was found that the best sensor response to NO was observed for the films of chlorinated derivatives MPcCl₄ (M = Co, Fe), while the lowest response was in the case of MPc(tBu)₄ films. FePcCl₄ films ex

SUBMITTER: Klyamer D 

PROVIDER: S-EPMC10136685 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature