Full-Quantum Treatment of Molecular Systems Confirms Novel Supracence Photonic Properties.

ABSTRACT: Our understanding of molecules has stagnated at a single quantum system, with atoms as Newtonian particles and electrons as quantum particles. Here, however, we reveal that both atoms and electrons in a molecule are quantum particles, and their quantum-quantum interactions create a previously unknown, newfangled molecular property-supracence. Molecular supracence is a phenomenon in which the molecule transfers its potential energy from quantum atoms to photo-excited electrons so that the emitted photon has more energy than that of the absorbed one. Importantly, experiments reveal such quantum energy exchanges are independent of temperature. When quantum fluctuation results in absorbing low-energy photons, yet still emitting high-energy photons, supracence occurs. This report, therefore, re

SUBMITTER: Wan W 

PROVIDER: S-EPMC10138974 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature