NMR-Relaxometric Investigation of Mn(II)-Doped Polyoxometalates in Aqueous Solutions.

ABSTRACT: Solution behavior of K;₅[(Mn(H₂O))PW₁₁O₃₉]·7H₂O (1), Na_3.66(NH₄)_4.74H_3.1[(Mn^II(H₂O))_2.75(WO(H₂O))_0.25(α-B-SbW₉O₃₃)₂]·27H₂O (2), and Na_4.6H_3.4[(Mn^II(H₂O)₃)₂(WO₂)₂(β-B-TeW₉O₃₃)₂]·19H₂O (3) was studied with NMR-relaxometry and HPLC-ICP-AES (High Performance Liquid Chromatography coupled with Inductively Coupled Plasma Atomic Emission Spectroscopy). According to the data, the [(Mn(H₂O))PW₁₁O₃₉]^5- Keggin-ty

SUBMITTER: Korenev VS 

PROVIDER: S-EPMC10139238 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature