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Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H₂ and N-H Activation by Metal-Ligand Cooperation as Key Steps.

ABSTRACT: Utilization of main-group metals as alternatives to transition metals in homogeneous catalysis has become a hot research area in recent years. However, their application in catalytic hydrogenation is less common due to the difficulty in heterolytic cleavage of the H-H bond. Employing aromatization/de-aromatization metal-ligand cooperation (MLC) highly enhances the H₂ activation process, offering an efficient approach for the hydrogenation of unsaturated molecules catalyzed by main-group metals. Herein, we report a series of new magnesium pincer complexes prepared using PNNH-type pincer ligands. The complexes were characterized by NMR and X-ray single-crystal diffraction. Reversible activation of H₂ and N-H bonds by MLC employing these pincer complexes was developed. U

SUBMITTER: Liang Y

PROVIDER: S-EPMC10141328 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature

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Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H₂ and N-H Activation by Metal-Ligand Cooperation as Key Steps.

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Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N-H Activation by Metal-Ligand Cooperation as Key Steps.

OmicsDI is part of the ELIXIR infrastructure

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Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H₂ and N-H Activation by Metal-Ligand Cooperation as Key Steps.