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A Trinuclear Gadolinium Cluster with a Three-Center One-Electron Bond and an S = 11 Ground State.

ABSTRACT: The recent discovery of metal-metal bonding and valence delocalization in the dilanthanide complexes (Cp^iPr5)₂Ln₂I₃ (Cp^iPr5 = pentaisopropylcyclopentadienyl; Ln = Y, Gd, Tb, Dy) opened up the prospect of harnessing the 4fⁿ5d_z²¹ electron configurations of non-traditional divalent lanthanide ions to access molecules with novel bonding motifs and magnetism. Here, we report the trinuclear mixed-valence clusters (Cp^iPr5)₃Ln₃H₃I₂ (1-Ln, Ln = Y, Gd), which were synthesized via potassium graphite reduction of the trivalent clusters (Cp^iPr5)₃Ln₃H₃I₃. Structural, computational, an

SUBMITTER: McClain KR

PROVIDER: S-EPMC10141408 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature

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A Trinuclear Gadolinium Cluster with a Three-Center One-Electron Bond and an S = 11 Ground State.

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