The Dichotomy of Mn-H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes.

ABSTRACT: Acid-base characteristics (acidity, pKa, and hydricity, ΔG°_H- or k_H-) of metal hydride complexes could be a helpful value for forecasting their activity in various catalytic reactions. Polarity of the M-H bond may change radically at the stage of formation of a non-covalent adduct with an acidic/basic partner. This stage is responsible for subsequent hydrogen ion (hydride or proton) transfer. Here, the reaction of tricarbonyl manganese hydrides mer,trans-[L₂Mn(CO)₃H] (1; L = P(OPh)₃, 2; L = PPh₃) and fac-[(L-L')Mn(CO)₃H] (3, L-L' = Ph₂PCH₂PPh₂ (dppm); 4, L-L' = Ph₂PCH₂-NHC) with organic bases and L

SUBMITTER: Osipova ES 

PROVIDER: S-EPMC10143952 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature