4-Mercaptopyridine-Modified Sensor for the Sensitive Electrochemical Detection of Mercury Ions.

ABSTRACT: As a highly toxic heavy metal ion, mercury ion (Hg²⁺) pollution has caused serious harm to the environment and human health. In this paper, 4-mercaptopyridine (4-MPY) was selected as the sensing material and decorated on the surface of a gold electrode. Trace Hg²⁺ could be detected by both differential pulse voltammetry (DPV) and electrochemical impedance spectroscopy (EIS) methods. The proposed sensor displayed a wide detection range from 0.01 μg/L to 500 μg/L with a low limit of detection (LOD) of 0.002 μg/L by EIS measurements. Combined with molecular simulations and electrochemical analyses, the chelating mechanism between Hg²⁺ and 4-MPY was explored. Through the analysis of binding energy (BE) values and stability constants, 4-MPY showed an excellent s

SUBMITTER: Han M 

PROVIDER: S-EPMC10143982 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature