DRIFTS-MS Investigation of Low-Temperature CO Oxidation on Cu-Doped Manganese Oxide Prepared Using Nitrate Aerosol Decomposition.

ABSTRACT: Cu-doped manganese oxide (Cu-Mn₂O₄) prepared using aerosol decomposition was used as a CO oxidation catalyst. Cu was successfully doped into Mn₂O₄ due to their nitrate precursors having closed thermal decomposition properties, which ensured the atomic ratio of Cu/(Cu + Mn) in Cu-Mn₂O₄ close to that in their nitrate precursors. The 0.5Cu-Mn₂O₄ catalyst of 0.48 Cu/(Cu + Mn) atomic ratio had the best CO oxidation performance, with T₅₀ and T₉₀ as low as 48 and 69 °C, respectively. The 0.5Cu-Mn₂O₄ catalyst also had (1) a hollow sphere morphology, where the sphere wall was composed of a large number of nanospheres (about 10 nm), (2) the largest specifi

SUBMITTER: Gong X 

PROVIDER: S-EPMC10144047 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature