Low-temperature electrolytes based on linear carboxylic ester co-solvents for SiO _x /graphite composite anodes.

ABSTRACT: Silicon-based anode materials have been applied in lithium-ion batteries with high energy density. However, developing electrolytes that can meet the specific requirements of these batteries at low temperatures still remains a challenge. Herein, we report the effect of linear carboxylic ester ethyl propionate (EP), as the co-solvent in a carbonate-based electrolyte, on SiO _x /graphite (SiOC) composite anodes. Using electrolytes with EP, the anode provides better electrochemical performance at both low temperatures and ambient temperature, showing a capacity of 680.31 mA h g^-1 at -50 °C and 0.1C (63.66% retention relative to that at 25 °C), and a capacity retention of 97.02% after 100 cycles at 25 °C and 0.5C. Within the EP-containing electrolyte, SiOC‖LiCoO

SUBMITTER: Wang R 

PROVIDER: S-EPMC10152230 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature