Stepwise Amplification of Circularly Polarized Luminescence in Chiral Metal Cluster Ensembles.

ABSTRACT: Chiral metal-organic frameworks (MOFs) are usually endowed by chiral linkers and/or guests. The strategy using chiral secondary building units in MOFs for solving the trade-off of circularly polarized luminescence (CPL)-active materials, high photoluminescence quantum yields (PLQYs) and high dissymmetry factors (|g_lum |) has not been demonstrated. This work directionally assembles predesigned chiral silver clusters with ACQ linkers through reticular chemistry. The nanoscale chirality of the cluster transmits through MOF's framework, where the linkers are arranged in a quasi-parallel manner and are efficiently isolated and rigidified. Consequently, this backbone of chiral cluster-based MOFs demonstrates superb CPL, high PLQYs of 50.3%, and |g_lum | of 1.2 × 10^-2

SUBMITTER: Wang JY 

PROVIDER: S-EPMC10161016 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature