(N-Benzoyl-N-phenyl-hydroxy-laminato)carbon-yl(tri-phenyl-arsine)rhodium(I).
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ABSTRACT: The mol-ecule of the title compound, [Rh(C13H10NO2){As(C6H5)3}(CO)] or [Rh(BPHA)(AsPh3)(CO)] (BPHA is the N-benzoyl-N-phenyl-hydroxy-laminate anion), comprises a bidentate N-benzoyl-N-phenyl-hydroxy-laminate anion coordinating through the O atoms to the soft Lewis acid, rhodium(I), and two monodentate ligands, viz. tri-phenyl-arsine and carbonyl. The resulting CO2As coordination environment around the central RhI atom is distorted square planar.=.
SUBMITTER: Motente MA
PROVIDER: S-EPMC10162025 | biostudies-literature | 2023 Apr
REPOSITORIES: biostudies-literature
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