Synthesis and crystal structure of catena-poly[[[aqua-{2-[(E)-(1-cyano-2-imino-2-meth-oxy-ethyl-idene)hydrazin-yl]benzene-sulfonato}-sodium]-di-μ-aqua] dihydrate].

ABSTRACT: In the polymeric title compound, {[Na(C₁₀H₉N₄O₄S)(H₂O)₃]·2H₂O} _n , sixfold coordinated Na⁺ cations are linked into a chain parallel to [010] by sharing common water mol-ecules. Next to the four bridging water mol-ecules, each Na⁺ cation of the chain is bonded to the O atom of a terminal water mol-ecule and an O atom of the SO₃ ^- group of the sulfonate anion. Classical O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds and additional π-π inter-actions connect these chains into a three-dimensional network.

SUBMITTER: Aliyeva VA 

PROVIDER: S-EPMC10162073 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature