Ultrahigh-rate and ultralong-life aqueous batteries enabled by special pair-dancing proton transfer.

ABSTRACT: The design of Faradaic battery electrodes with high rate capability and long cycle life comparable to those of supercapacitors is a grand challenge. Here, we bridge this performance gap by taking advantage of a unique ultrafast proton conduction mechanism in vanadium oxide electrode, developing an aqueous battery with untrahigh rate capability up to 1000 C (400 A g^-1) and extremely long life of 0.2 million cycles. The mechanism is elucidated by comprehensive experimental and theoretical results. Instead of slow individual Zn²⁺ transfer or Grotthuss chain transfer of confined H⁺, the ultrafast kinetics and excellent cyclic stability are enabled by rapid 3D proton transfer in vanadium oxide via the special pair dance switching between Eigen and Zundel configu

SUBMITTER: Wang L 

PROVIDER: S-EPMC10162668 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature