Origin of dendrite-free lithium deposition in concentrated electrolytes.

ABSTRACT: The electrolyte solvation structure and the solid-electrolyte interphase (SEI) formation are critical to dictate the morphology of lithium deposition in organic electrolytes. However, the link between the electrolyte solvation structure and SEI composition and its implications on lithium morphology evolution are poorly understood. Herein, we use a single-salt and single-solvent model electrolyte system to systematically study the correlation between the electrolyte solvation structure, SEI formation process and lithium deposition morphology. The mechanism of lithium deposition is thoroughly investigated using cryo-electron microscopy characterizations and computational simulations. It is observed that, in the high concentration electrolytes, concentrated Li⁺ and anion-dominated

SUBMITTER: Chen Y 

PROVIDER: S-EPMC10169806 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature