Effect of air bubbling on electroless Pd plating for the practical application of hydrogen selective membranes.

ABSTRACT: In this study, an air bubbling electroless plating (ELP) method was newly developed for the production of Pd composite membranes. The air bubble ELP alleviated the concentration polarization of Pd ions, making it possible to achieve a plating yield of 99.9% in 1 h and form very fine Pd grains with a uniform layer of ∼4.7 μm. A membrane with a diameter of 25.4 mm and a length of 450 mm was produced by the air bubbling ELP, achieving a hydrogen permeation flux of 4.0 × 10^-1 mol m^-2 s^-1 and selectivity of ∼10 000 at 723 K with a pressure difference of 100 kPa. To confirm the reproducibility, six membranes were produced by the same method and assembled in a membrane reactor module to produce high-purity hydrogen by ammonia decomposition. Hydrogen permeation flu

SUBMITTER: Lee EH 

PROVIDER: S-EPMC10170241 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature