On the existence of low-valent magnesium-calcium complexes.

ABSTRACT: DFT-Calculations predict that a low-valent complex (BDI)Mg-Ca(BDI) with bulky β-diketiminate (BDI) ligands is thermodynamically stable. It was attempted to isolate such a complex by salt-metathesis between [(^DIPePBDI*)Mg^-Na⁺]₂ and [(^DIPePBDI)CaI]₂ (^DIPePBDI = HC[C(Me)N-DIPeP]₂; ^DIPePBDI* = HC[C(tBu)N-DIPeP]₂; DIPeP = 2,6-CH(Et)₂-phenyl). Whereas in alkane solvents no reaction was observed, salt-metathesis in C₆H₆ led to immediate C-H activation of benzene to give (^DIPePBDI*)MgPh and (^DIPePBDI)CaH, the latter crystallizing as a THF-solvated dimer [(^DIPePBDI)CaH·THF]₂. Calculations suggest reduction a

SUBMITTER: Mai J 

PROVIDER: S-EPMC10171184 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature