Nearly 100% selective and visible-light-driven methane conversion to formaldehyde via. single-atom Cu and W^δ.

ABSTRACT: Direct solar-driven methane (CH₄) reforming is highly desirable but challenging, particularly to achieve a value-added product with high selectivity. Here, we identify a synergistic ensemble effect of atomically dispersed copper (Cu) species and partially reduced tungsten (W^δ+), stabilised over an oxygen-vacancy-rich WO₃, which enables exceptional photocatalytic CH₄ conversion to formaldehyde (HCHO) under visible light, leading to nearly 100% selectivity, a very high yield of 4979.0 μmol·g^-1 within 2 h, and the normalised mass activity of 8.5 × 10⁶ μmol·g^-1_Cu·h^-1 of HCHO at ambient temperature. In-situ EPR and XPS analyses indicate that the Cu species serve as the electron acceptor, promoting

SUBMITTER: Luo L 

PROVIDER: S-EPMC10172301 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature