Anion Exchange Membranes Based on Bis-Imidazolium and Imidazolium-Functionalized Poly(phenylene oxide) for Vanadium Redox Flow Battery Applications.

ABSTRACT: Although the Nafion membrane has a high energy efficiency, long service life, and operational flexibility when applied for vanadium redox flow battery (VRFB) applications, its applications are limited due to its high vanadium permeability. In this study, anion exchange membranes (AEMs) based on poly(phenylene oxide) (PPO) with imidazolium and bis-imidazolium cations were prepared and used in VRFBs. PPO with long-pendant alkyl-side-chain bis-imidazolium cations (BImPPO) exhibits higher conductivity than the imidazolium-functionalized PPO with short chains (ImPPO). ImPPO and BImPPO have a lower vanadium permeability (3.2 × 10^-9 and 2.9 × 10^-9 cm² s^-1) than Nafion 212 (8.8 × 10^-9 cm² s^-1) because the imidazolium cati

SUBMITTER: Li J 

PROVIDER: S-EPMC10173422 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature