Extracting Features of Active Transition Metal Electrodes for NO Electroreduction with Catalytic Matrices.

ABSTRACT: Electrocatalytic reduction of oxidized nitrogen compounds (NO_x) promises to help rebalance the nitrogen cycle. It is widely accepted that nitrate reduction to NH₄⁺/NH₃ involves NO as an intermediate, and NO hydrogenation is the potential-limiting step of NO reduction. Whether *NO hydrogenates to *NHO or *NOH is still a matter of debate, which makes it difficult to optimize catalysts for NO_x electroreduction. Here, "catalytic matrices" are used to swiftly extract features of active transition metal catalysts for NO electroreduction. The matrices show that active catalysts statistically stabilize *NHO over *NOH and have undercoordinated sites. Besides, square-symmetry active sites with Cu and other elements may prove

SUBMITTER: Romeo E 

PROVIDER: S-EPMC10176317 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature