Dynamics of the Ligand Excited States Relaxation in Novel β-Diketonates of Non-Luminescent Trivalent Metal Ions.

ABSTRACT: Complexes emitting in the blue spectral region are attractive materials for developing white-colored light sources. Here, we report the luminescence properties of novel coordination compounds based on the trivalent group 3, 13 metals, and the 1-phenyl-3-methyl-4-cyclohexylcarbonyl-pyrazol-5-onate (Q^CH) ligand. [M(Q^CH)₃] (M = Al, Ga, and In), [M(Q^CH)₃(H₂O)] (M = Sc, Gd, and Lu), [Lu(Q^CH)₃(DMSO)], and [La(Q^CH)₃(H₂O)(EtOH)] complexes were synthesized and structurally characterized by a single-crystal X-ray diffraction study. It has been found that the luminescence quantum yields of the ligand increase by one order of magnitude upon metal coordination. A significant correspo

SUBMITTER: Polikovskiy T 

PROVIDER: S-EPMC10179517 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature