Engineering Cu/NiCu LDH Heterostructure Nanosheet Arrays for Highly-Efficient Water Oxidation.

ABSTRACT: The development of stable and efficient electrocatalysts for oxygen evolution reaction is of great significance for electro-catalytic water splitting. Bimetallic layered double hydroxides (LDHs) are promising OER catalysts, in which NiCu LDH has excellent stability compared with the most robust NiFe LDH, but the OER activity is not satisfactory. Here, we designed a NiCu LDH heterostructure electrocatalyst (Cu/NiCu LDH) modified by Cu nanoparticles which has excellent activity and stability. The Cu/NiCu LDH electrocatalyst only needs a low over-potential of 206 mV and a low Tafel slope of 86.9 mV dec^-1 at a current density of 10 mA cm^-2 and maintains for 70 h at a high current density of 100 mA cm^-2 in 1M KOH. X-ray photoelectron spectroscopy (XPS) showed th

SUBMITTER: Wang AB 

PROVIDER: S-EPMC10179677 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature