Polyketone-Based Anion-Exchange Membranes for Alkaline Water Electrolysis.

ABSTRACT: Anion-exchange membranes (AEMs) are involved in a wide range of applications, including fuel cells and water electrolysis. A straightforward method for the preparation of efficient AEMs consists of polymer functionalization with robust anion-exchange sites. In this work, an aliphatic polyketone was functionalized with 1-(3-aminopropyl)imidazole through the Paal-Knorr reaction, with a carbonyl (C_CO %) conversion of 33%. The anion-exchange groups were generated by the imidazole quaternization by using two different types of alkyl halides, i.e., 1,4-iodobutane and 1-iodobutane, with the aim of modulating the degree of crosslinking of the derived membrane. All of the membranes were amorphous (T_g ∼ 30 °C), thermally resistant up to 130 °C, and had a minimum Young's modulus

SUBMITTER: Racchi O 

PROVIDER: S-EPMC10180749 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature