A-Site Cation Dependence of Self-Healing in Polycrystalline APbI₃ Perovskite Films.

ABSTRACT: In terms of sustainable use, halide perovskite (HaP) semiconductors have a strong advantage over most other classes of materials for (opto)electronics, as they can self-heal (SH) from photodamage. While there is considerable literature on SH in devices, where it may not be clear exactly where damage and SH occur, there is much less on the HaP material itself. Here we perform "fluorescence recovery after photobleaching" (FRAP) measurements to study SH on polycrystalline thin films for which encapsulation is critical to achieving complete and fast self-healing. We compare SH in three photoactive APbI₃ perovskite films by varying the A-site cation ranging from (relatively) small inorganic Cs through medium-sized MA to large FA (the last two are organic cations). While the A cation

SUBMITTER: Singh P 

PROVIDER: S-EPMC10189583 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature