Synthesis and In Situ Monitoring of Mechanochemical Preparation of Highly Proton Conductive Hydrogen-Bonded Metal Phosphonates.

ABSTRACT: Crystalline porous materials are recognized as promising proton conductors for the proton exchange membrane (PEM) in fuel cell technology owing to their tunable framework structure. However, it is still a challenging bulk synthesis for real-world applications of these materials. Herein, we report the mechanochemical gram-scale synthesis of two isostructural metal hydrogen-bonded organic frameworks (MHOFs) of Co(II) and Ni(II) based on 1-hydroxyethylidenediphosphonic acid (HEDPH₄) with 2,2'-bipyridine (2,2'-bipy): Co(HEDPH₃)₂(2,2'-bipy)·H₂O (1) and Ni(HEDPH₃)₂(2,2'-bipy)·H₂O (2). In situ monitoring of the mechanochemical synthesis using different synchrotron-based techniques revealed a one-step

SUBMITTER: Akhmetova I 

PROVIDER: S-EPMC10193405 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature