Highly selective CO₂ photoreduction to CO on MOF-derived TiO₂.

ABSTRACT: Metal-Organic Framework (MOF)-derived TiO₂, synthesised through the calcination of MIL-125-NH₂, is investigated for its potential as a CO₂ photoreduction catalyst. The effect of the reaction parameters: irradiance, temperature and partial pressure of water was investigated. Using a two-level design of experiments, we were able to evaluate the influence of each parameter and their potential interactions on the reaction products, specifically the production of CO and CH₄. It was found that, for the explored range, the only statistically significant parameter is temperature, with an increase in temperature being correlated to enhanced production of both CO and CH₄. Over the range of experimental settings explored, the MOF-derived TiO

SUBMITTER: Garvin M 

PROVIDER: S-EPMC10193832 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature