Superior ferroelectricity and nonlinear optical response in a hybrid germanium iodide hexagonal perovskite.

ABSTRACT: Abundant chemical diversity and structural tunability make organic-inorganic hybrid perovskites (OIHPs) a rich ore for ferroelectrics. However, compared with their inorganic counterparts such as BaTiO₃, their ferroelectric key properties, including large spontaneous polarization (P_s), low coercive field (E_c), and strong second harmonic generation (SHG) response, have long been great challenges, which hinder their commercial applications. Here, a quasi-one-dimensional OIHP DMAGeI₃ (DMA = Dimethylamine) is reported, with notable ferroelectric attributes at room temperature: a large P_s of 24.14 μC/cm² (on a par with BaTiO₃), a low E_c below 2.2 kV/cm, and the strongest SHG intensity in OIHP family (about 12

SUBMITTER: Ding K 

PROVIDER: S-EPMC10199078 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature