Pressure dependence in aqueous-based electrochemical CO₂ reduction.

ABSTRACT: Electrochemical CO₂ reduction (CO₂R) is an approach to closing the carbon cycle for chemical synthesis. To date, the field has focused on the electrolysis of ambient pressure CO₂. However, industrial CO₂ is pressurized-in capture, transport and storage-and is often in dissolved form. Here, we find that pressurization to 50 bar steers CO₂R pathways toward formate, something seen across widely-employed CO₂R catalysts. By developing operando methods compatible with high pressures, including quantitative operando Raman spectroscopy, we link the high formate selectivity to increased CO₂ coverage on the cathode surface. The interplay of theory and experiments validates the mechanism, and guides us to functionalize the s

SUBMITTER: Huang L 

PROVIDER: S-EPMC10205702 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature